119 results found for chemistry

band structures and band gap engineering

Photodynamic Therapy

Photophysics & State Energy Diagram

Plasmonics

Workshop

Temperature responsive polymer is an interesting material that shows reversible hydration/dehydration behavior in water at 32C, termed as the lower critical solution temperature (LCST). In this video, temperature responsive block copolymers are focus....

Eric Betzig shared the 2014 Chemistry Nobel prize with fellow American William E. Moerner and Romanian-German Stefan W. Hell for revolutionising science through the development of super-resolved fluorescence to exceed the accepted limits of tradition....

The development of radio telescopes has revolutionized our understanding of the molecular constitution of the interstellar medium ISM. A recent surprise that the element carbon had up its sleeve was the existence of C60, Buckminsterfullerene, the thi....

More than 25 years ago, single molecules were first detected optically, but how do we really detect a single molecule today, and what good is it? It is an amazing fact that you can even detect single molecules with your own eyes. When a new regime of....

Intermittently fluorescing single molecule systems are found in many materials, including semiconductor quantum dots (QD), dyes on crystalline or nanoparticle film surfaces, and biological systems. The QD's show a ~ -3/2 power law for the distributio....

For cancer diagnosis and therapy, we are developing activatable cell penetrating peptides (ACPPs), synthetic molecules with a novel amplifying mechanism for homing to diseased tissues. ACPPs are polycationic cell penetrating peptides whose cellular u....

For the discovery of the physics phenomenon of nuclear magnetic resonance (NMR), Felix Bloch and Edward Purcell were awarded the Nobel Prize in Physics in 1952. NMR has then been used in a wide range of fundamental studies in physics, and in the 1960....

The discovery and synthetic applications of a widely applicable and highly enantioselective (>99% ee) protocol consisting of the 'ZACA reaction' (Zr-catalyzed asymmetric carboalumination of alkenes), purification of the ZACA-products by lipase-cat....

This lecture addresses the question if spatio-temporal self-organisation of matter which is so characteristic for living systems can also be verified with a simple inorganic reaction in which the observed phenomena of complexity can be traced back to....

The selective degradation of many short-lived proteins in eukaryotic cells is carried out by the ubiquitin-mediated proteolytic system. In this pathway, proteins are targeted for degradation by covalent ligation to ubiquitin, a highly conserved small....

This lecture starts out with a very brief review of the history of protein crystallography and continue with our studies since 1970 on proteolytic enzymes and their control. Proteolytic enzymes catalyse a very simple chemical reaction, the hydrolytic....

Molecular chemistry implementing reversible chemical bonds between atoms in molecules, as well as supramolecular chemistry, whose molecular components are held together by intermolecular interactions, are able to undergo a continuous change in consti....

Aquaporin channels allow water to rapidly cross cell membranes in all living organisms. AQP1 confers red cells and proximal renal tubules with high water permeability. Present in renal collecting duct, AQP2 is regulated by vasopressin, and human muta....

It has been a hundred years since molecules were first visualized directly by using x-ray crystallography. That gave us our first look at molecules as simple as common salt to one as complex as the ribosome that has almost a million atoms. In the las....

When he received the 1996 Nobel Prize in Chemistry together with Richard E. Smalley (who also worked at Rice) and Sir Harold Kroto (at the time at the University of Sussex, UK), this was a true example of national and international scientific collabo....

Fundamental aspects and properties of fuel cells in the environment of renewables.

Know the basics of electrochemical fuel cells and batteries

Learn the basics of a fuel cell

Know the most important criteria for the classification of the fuel cells

Most used fuel in fuel cells, the advantages of their use and limitations

Basic characteristics of the batteries based on proton exchange membrane

Understand the transport phenomena that take place in the membranes used in PEMFC

Criteria to classify Fuel Cells

Understand the advantages and limitations of using hydrogen in fuel cells

Most important applications in the field of fuel cells

Understanding the phenomena that cause the reduction in efficiency that occurs in the fuel cell operation

Polarization curves of the fuel cells, and the phenomena which cause a decline in energy efficiency

Methanol fuel cells (DMFC), its rationale and the advantages and limitations of their use over other fuel cells

Fundamental aspects of Alkaline Fuel Cells

In part three of this three part series, FSU chemist Dr. Gregory Dudley, summarizes the conclusions of ongoing FSU microwave chemistry research. He discusses the implications and future prospects of microwave research, addressing how other labs could....

In part two of this three part series, FSU chemist Dr. Gregory Dudley, discusses in depth the microwave chemistry research he's conducted in collaboration with FSU colleague Dr. Al Stiegman. The research outlines Friedel-Crafts substitutions, Aryl-Cl....

In part one of this three part series, FSU chemist Dr. Gregory Dudley, puts forth the controversy that surrounds microwave chemistry research, he outlines physical theory of microwave chemistry, and discusses the research teams central design hypothe....

This is the introduction to a three part research presentation on microwave chemistry given by FSU chemist Dr. Gregory Dudley. Dudley reports on joint FSU research surrounding microwave chemistry and its previously unknown potential in lab applicatio....

Introduction and short review of fuel cells

Brief review of electrochemical basis of fuel cells

Every macroscopic chemical transformation, whether it is atmospheric ozone depletion or the burning of a candle, consists of millions of microscopic chemical events, which involve collisions between molecules.  It has been the dream of scientists fo....

Our experience suggests that a system will usually show the tendency to undergo spontaneously a transition from the state of order into disorder.  Quite in contrast, our world developed from an initial state of great disorder into another one where ....

Science is inevitably intertwined with society.  The state of the art of science, coupled with industrial endeavors, has determined our quality of life.  Chemists are proud of their ability to generate high value from almost nothing by using accumu....

Molecules to observe and manipulate biological systems can be devised by a variety of strategies, ranging from pure chemical design and total synthesis to genome mining and high-throughput directed evolution. Examples of both successes and failures a....

We live in a fascinating world surrounded by life. Much of that life is clearly visible like the plants and animals that we see every day. However, far more is invisible to the naked eye and it is to this realm, the microscopic world, that I will t....

Survival of vertebrate hosts against infections depends on important natural or innate resistance mechanisms combined with adaptive immune responses of T and B cells. Infectious agents probe the limit of immune responses and help to characterize thr....

After a short reminder of the historical development of evolutionary biology, elements to a molecular theory of Darwinian evolution will be presented. Biological evolution is driven by the availability of genetic variants in populations. The occasi....

This talk concentrates on cellular regulation by tyrosine phosphorylation which has been directly implicated in cell growth, differentiation and transformation. Growth factor receptors transduce their signal by recruiting a multiplicity of adaptor p....

It was in 1882 that Walther Flemming published drawings of chromosomes lining up in mitosis and parting equally to the daughters of cell division, and 20 years later that Theodor Boveri explained the significance of the chromosome dance in terms of t....

Argonaute proteins interact with small RNAs to mediate gene silencing. C. elegans contains 27 Argonaute homologs, raising the question of what roles these genes play in RNAi and related gene-silencing pathways. Through our collaborator, Dr. Shohei....

The role of nitric oxide in cellular signaling in the past three decades has become one of the most rapidly growing areas in biology. Nitric oxide is a gas and a free radical with an unshared electron that can regulate an ever-growing list of biolog....

In the process of preparing M(NR)(CHCMe2R')(OR")2 (R' = Me or Ph) species (or analogs that contain enantiomerically pure biphenolate or binaphtholate ligands) in situ by treating M(NR)(CHCMe2R')(pyrrolide)2 species with alcohols, we have discovered M....

Much of theoretical chemistry has involved equations and their application to experiments, Debye, Debye-Hueckel, Transition State Theory, Kramers, LCAO, RRKM, among others. In fortunate circumstances one can, as in a theory of electron transfer reac....

Chemistry is not merely a science of making observations in order to better understand Nature. Our science is creative and productive, generating substances of very high value from almost nothing. Chemists already have made enormous contribution to....

The 'greenhouse gases (GHG)' intercept a fraction of outgoing terrestrial infrared radiation, creating the natural greenhouse effect which warmed the atmosphere by approximately 32 Celsius at the beginning of the 20th Century. The activities of manki....

The interaction of molecules with the surfaces of solids forms the basis of heterogeneous catalysis and can now be investigated in atomic detail. Systems of this kind may, on the other hand, serve as models for studying self-organisation of matter le....

Despite their relatively small mass, 10% of the earth biosphere as a whole, generations of ambitious ‘homo sapiens’ have already played a major and increasing role in changing basic properties of the atmosphere and the earth’s surface.  Human ....

It is generally accepted that the global warming, which we undoubtedly observe, is the result of an increased concentration of greenhouse gases like carbon dioxide and methane in the atmosphere.  Within this scenario it is evident that we have to re....

Until recently, most of the 24 d-block transition metals had been used primarily as useful materials for (i) construction and also as tools and containers, etc., (Ti, Zr, Fe and their alloys with V, Cr, Mn, Co, Ni, etc.), (ii) precious and ornamental....

In an evangelical spirit, three vignettes will be presented that have the character of molecular parables: stories with lessons that transcend the specific details.(1) How knowledge of the orientation of a methyl group with respect to a neighboring d....

Catalysis by solid surfaces is, among others, of importance for the chemical industry (e.g. the Haber-Bosch process) as well as for environmental chemistry (car exhaust catalyst).  Surface physical techniques enable investigation of the underlying e....

The palladium-catalyzed cross-coupling reaction between different types of organoboron compounds and various organic halides in the presence of base provides a powerful and general methodology for the formation of carbon-carbon bonds.  The (sp3)C-B ....

G protein coupled receptors (GPCRs) conduct the majority of cellular responses to hormones and neurotransmitters, and are therefore the largest group of pharmaceutical targets for a broad spectrum of diseases.  Identification of genes for GPCRs, ini....

Olefin metathesis is an irresistible way to make C=C bonds catalytically in organic molecules and polymers, both as a consequence of its very nature, i.e. the synthesis of C=C bonds from C=C bonds, and because of the control that can be exercised thr....

Much of the chemical industry is based on processes that were developed decades ago.  The change in the cost of petroleum carbon and energy sources and the need to control emissions of carbon dioxide and other pollutants will change the rules of the....

Supramolecular chemistry lies beyond molecular chemistry.  It aims at implementing highly complex chemical systems from molecular components held together by non-covalent intermolecular forces and effecting molecular recognition, catalysis and trans....

We consider two fields of single molecule studies of intermittently fluorescing systems.  In both fields the intermittency is assumed to involve diffusion controlled electron transfer.  One of these studies involves the initial steps in dye-sensiti....

Some observers might think that fierce scientific competition borders on a rat race.  According to Wikipedia: "A rat race is an endless, self-defeating, or pointless pursuit.  It conjures up the image of the futile efforts of a lab rat trying to es....

Florida State graduate student Brian Gold discusses his research into click chemistry, that is building complex molecules using simple reactions that always work. Brian's project focuses on increasing ring strain of organic molecules without reducing....

Kristen Pace presenting her research at the FSU Research Remix

Duke University

Brahatheeswaran describes how tissue scaffolds can be made in novel ways.  This lecture is his PhD thesis defence.

During his PhD thesis defence, Ankur looks at the ways in which various techniques are used for the creation of the desired structural characteristics of carbon nanotubes  

Peter Agre shared the 2003 Nobel Prize in Chemistry with Roderick MacKinnon “for discoveries concerning channels in cell membranes.” Here he gives a lecture in Russia as part of the Nobel Prize Inspiration Initiative

The discoverer of these really useful reactions talks about their discovery and development.

Alan Marshall describes how the ultra-high resolution, obtainable with very large magnetic fields, of Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FT-ICR MS) enables rapid and accurate analysis of very complex mixtures.

Philip Shlenoff, recent high school graduate, gives a presentation of his work and opportunity at the Florida State University Dept. of Chemistry. Under the supervision of Zaki Estephan, Philip has actively participated in research that targets canc....

Microwave chemistry is a field that is growing in popularity. Microwave radiation offers a more efficient means of heating compared to traditional thermal processes. The added efficiency comes from the idea of selective heating. It is important to un....

Five years ago this summer (in 1999), the Royal Society and the Royal Academy of Engineering issued a report on Nanoscience and nanotechnologies: opportunities and uncertainties. The report had been commissioned by the Government, and has been widely....

In 1959, Richard Feynman proposed a variety of new nano-tools including the concept of atom by atom' fabrication. In the intervening decades, many of these predictions have become reality. Andrew de Mello assesses the current impact of lab-on-a-chip ....

Brian Gold presents on the geometry, mathematics, and applications of group theory in chemical fingerprinting.